SXMS_NV_S is an SAP Structure so does not store data like a database table does but can be used to process "Name Value Structure" Information within sap ABAP programs. This is done by declaring abap internal tables, work areas or database tables based on this Structure. These can then be used to store and process the required data appropriately.
i.e. DATA: wa_SXMS_NV_S TYPE SXMS_NV_S .
Below is the documentation avaialable and full details of the fields which make up this Structure.
|Data Type||length (Decimals)||Check table||Description||Conversion Routine|